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Cathodic reduction of diazonium salts in aprotic medium
Authors:Fructuoso Barba  Belen Batanero  Khalil Tissaoui  Noureddine Raouafi  Khaled Boujlel
Affiliation:1. Department of Organic Chemistry, University of Alcala, 28871 Alcala de Henares (Madrid), Spain;2. Laboratoire de Chimie Analytique et d´Electrochimie, 2092 El-Manar, Tunis, Tunisia
Abstract:Cathodic reduction of diazonium salts in acetonitrile led to the formation of azobenzenes, in good to moderate yields, and diarylamines as minoritary products. The reactions were carried out at the second reduction potential of the diazonium salts, involving aryl anions in the formation of the products.
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