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Charge-transfer complexes of 4-nitrocatechol with some amino alcohols
Authors:Sahar Baniyaghoob  Mohammad Mahdi Najafpour  Davar M Boghaei
Institution:Department of Chemistry, Sharif University of Technology, Azadi Ave., P.O. Box 11155-3516, Tehran, Iran
Abstract:Charge-transfer (CT) complexes formed from the reactions of 4-nitropyrocatechol (4-nCat) as an electron acceptor with four amino alcohols: 2-aminoethanol, 1-amino-2-propanol, 4-aminobutanol and N-(2-hydroxyethyl)-1,3-diaminopropane (NHEDAP) as electron donors, have been studied spectrophotometrically in H2O and H2O/EtOH at 20, 25, 30, 35 and 40 °C. The calculated values of the oscillator strength and transition moment confirm the formation of CT-complexes. The thermodynamic and spectroscopic parameters were also evaluated for the formation of CT-complexes. The equilibrium constants ranged from 9.00 to 2.20 l mol?1 (M?1). These interactions are exothermic and have relatively large standard enthalpy and entropy changes (ΔH values ranged from ?15.58 to ?3.10 kJ mol?1; ΔS ranged from 26.81 to ?3.25 J K?1 mol?1). The solid CT-complexes have been synthesized and characterized by IR, NMR, mass spectrometry and thermal analysis. The photometric titration curves and other spectrometric data for the reactions indicated that the data obtained refer to the formation of 1:1 charge-transfer complex of (4-nCat) (NHEDAP)] and 1:2 charge-transfer complexes of other amino alcohols (4-nCat) (amino alcohol)2]. The effect of alkali and alkaline earth metals on increasing the equilibrium constant of the CT-complexation was also investigated.
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