Comparison of Birch with electrochemical reduction of 2,3-diphenyl-1,4-diazaspiro[4.5]deca-1,3-diene |
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| Authors: | Yan Zhou Anna Andreou Eldar Biktagirov Jason Eames Jay Wadhawan |
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| Affiliation: | Department of Physical Sciences (Chemistry), The University of Hull, Cottingham Road, Kingston-upon-Hull HU6 7RX, United Kingdom |
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| Abstract: | Reduction of 2,3-diphenyl-1,4-diazaspiro[4.5]deca-1,3-diene is investigated both voltammetrically (glassy-carbon electrode, 20 °C, non-aqueous-solvents) and using dissolving-metals (sodium, ?78 °C, tetrahydrofuran (THF)/NH3(l)). Remarkably, electro-reduction furnishes two two-electron processes, whilst only a four-electron product results from Birch synthesis. |
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