Synthesis,crystal structures,characterization and antimicrobial activities of 5-hydroxyisophthalate complexes |
| |
| Authors: | Alper Tolga Çolak Handan Günay Ersin Temel Orhan Büyükgüngör Ferdağ Çolak |
| |
| Institution: | 1.Department of Chemistry, Faculty of Arts and Sciences,Dumlup?nar University,Kutahya,Turkey;2.Department of Chemistry Technology, Vocational High School,Avrasya University,Pelitli,Turkey;3.Department of Electric and Energy, Technical Sciences Vocational High School,Giresun University,Giresun,Turkey;4.Department of Physics, Faculty of Arts and Sciences,Ondokuz May?s University,Kurupelit,Turkey;5.Department of Biology, Faculty of Arts and Sciences,Dumlup?nar University,Kutahya,Turkey |
| |
| Abstract: | Two 5-hydroxyisophthalate complexes of nickel(II), formulated as Ni(μ-Hhip)(2-hepy)2] n (1) and Ni2(μ-Hhip)2(dap)4] n (2) (H3hip = 5-hydroxyisophthalic acid, 2-hepy = 2-(2-hydroxyethyl)pyridine, dap = 1,3-diaminopropane), have been synthesized and characterized by chemical and spectroscopic methods. The molecular structures of the complexes have been determined by single-crystal X-ray diffraction analysis. The Ni(II) centres have distorted octahedral geometries in both crystals. Furthermore, both complexes have 1D chain structures in which the individual chains are linked together via hydrogen bonds to give 3D frameworks. Evaluation of the complexes by the agar diffusion method showed that they have weak antibiotic activities against the tested microorganisms. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
