Ferroelectric heterobimetallic clusters with ferromagnetic interactions |
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| Authors: | Wang Cai-Feng Gu Zhi-Guo Lu Xiao-Mei Zuo Jing-Lin You Xiao-Zeng |
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| Affiliation: | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. |
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| Abstract: | Two homochiral trinuclear clusters, {(MeTp)2Fe2(CN)6Ni[(1R,2R)-chxn]2} (1) and {(MeTp)2Fe2(CN)6Ni[(1S,2S)-chxn]2} (2) [chxn = 1,2-diaminocyclohexane; MeTp = methyltris(pyrazolyl)borate], have been synthesized and structurally characterized. Ferroelectric and magnetic measurements reveal that they are rare examples of metal-organic compounds bearing ferroelectricity and intramolecular ferromagnetic interactions. |
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