| 吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征 |
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| 引用本文： | 张俊勇,涂超,林骏,Hoong-Kun Fun,SuchadChantrapromm,游效曾,郭子建. 吡啶酰胺在Cd(Ⅱ)存在下的醇解反应及结构表征[J]. 无机化学学报, 2002, 18(6): 554-558 |
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| 作者姓名： | 张俊勇 涂超 林骏 Hoong-Kun Fun SuchadChantrapromm 游效曾 郭子建 |
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| 作者单位： | 南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia,Penang 11800, Malaysia,X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia,Penang 11800, Malaysia;Department of Chemistry, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.29925102)。 |
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| 摘 要： | X-射线晶体结构分析表明,在90℃的水热条件下,N-(8-喹啉基)吡啶-3-酰胺在Cd2+的存在下发生醇解。醇解产物为8-氨基喹啉(HL1)和吡啶-3-羧乙酯(HL2),它们与Cd(Ⅱ)配位形成四方锥型化合物。该配合物为单斜晶系,空间群P21/c,a=18.1089(1)?,b=8.9986(1)?,c=19.3070(2)?,β=113.085(1
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| 关 键 词： | 酰胺 晶体结构 水热合成 醇解 |
StructuralCharacterization for Alcoholysis of N-(8-Quinolyl)Pyridine-3-Carboxamide at the Presenceof Cd ( |
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| ZHANG Jun-Yong,TU Chao,LIN Jun,Hoong-Kun Fun,Suchad Chantrapromm,YOU Xiao-Zeng and GUO Zi-Jian. StructuralCharacterization for Alcoholysis of N-(8-Quinolyl)Pyridine-3-Carboxamide at the Presenceof Cd ([J]. Chinese Journal of Inorganic Chemistry, 2002, 18(6): 554-558 |
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| Authors: | ZHANG Jun-Yong TU Chao LIN Jun Hoong-Kun Fun Suchad Chantrapromm YOU Xiao-Zeng GUO Zi-Jian |
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| Affiliation: | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia,Penang 11800, Malaysia,X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia,Penang 11800, Malaysia;Department of Chemistry, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand,State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 |
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| Abstract: | |
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| Keywords: | amide crystal structure hydrothermal synthesis alcoholysis |
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