| 3-甲基-4-对甲基苯基-5-(2-吡啶基)-1，2，4-三唑双核锰(Ⅱ)配合物的合成及晶体结构 |
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| 引用本文： | 王作祥,徐海军,宫晓宁,吴平锋.3-甲基-4-对甲基苯基-5-(2-吡啶基)-1，2，4-三唑双核锰(Ⅱ)配合物的合成及晶体结构[J].无机化学学报,2009,25(5):906-909. |
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| 作者姓名： | 王作祥 徐海军 宫晓宁 吴平锋 |
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| 作者单位： | 东南大学化学化工学院有序物质科学研究中心,南京,211189 |
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| 摘 要： | A dinuclear Mn(Ⅱ) complex Mn2L2(μ-Cl)2Cl2(H2O)2] (1) was synthesized by reaction of ligand L with MnCl2 ·4H2O and its structure was determined by X-ray crystal structure analysis. The structure indicates that the complex crystallizes in monoclinic, space group C2/c with a=2.018 0(15) nm, b=0.894 0(6) nm, c=1.932 1(14) nm, β=97.506(12)°. V=3 456(4) nm3, Z=4, Dc=1.515 Mg·m-3, μ=1.081 mm-1, F(000)=1 608, and final R1=0.043 8, wR2=0.109 9. The result shows a Mn(Ⅱ) ion was six-coordinated by a bidentate 3-methyl-4-( p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole, one chlorine and one bridging chlorine atom in the basal positions and one chloride atom and one water molecule in the axial one, to form a distorted octahedral-pyramidal geometry. CCDC: 713047.
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| 关 键 词： | 1，2，4-三唑 晶体结构 双核锰配合物 |
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