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Comparing intermediate range order for alkyl- vs. ether-substituted cations in ionic liquids
Authors:Triolo Alessandro  Russina Olga  Caminiti Ruggero  Shirota Hideaki  Lee Heather Y  Santos Cherry S  Murthy N Sanjeeva  Castner Edward W
Institution:Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, Area della Ricerca di Tor Vergata, Rome, Italy. triolo@ism.cnr.it
Abstract:X-ray scattering data from four pairs of ionic liquids (ILs) are compared. The alkyl-substituted cations show a first sharp diffraction peak between 3 and 4 nm(-1) that is not observed for ILs having cations with ether- or hydroxy-substitutions. These observations indicate a significant difference in the intermediate range order for these liquids.
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