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Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions
Authors:Xiao Bin  Li Yi-Ming  Liu Zhao-Jing  Yang Han-Yi  Fu Yao
Affiliation:Department of Chemistry, Joint Laboratory of Green Synthetic Chemistry, University of Science and Technology of China, Hefei 230026, PR China.
Abstract:A practical Pd-catalyzed reaction was developed to achieve C-H activation/C-B cross-coupling of acetanilides under acidic conditions. The new reaction shows a good functional group tolerance and an exclusive mono-selectivity. This C-H borylation method may provide a generally applicable route for the conversion of C-H moieties into many other types of bonds.
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