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Extraction and analysis of arsenic in soils and sediments
Authors:K. A. Hudson-Edwards   S. L. Houghton  A. Osborn
Affiliation:School of Earth Sciences, Birkbeck College, University of London, Malet Street, London WC1E 7HX, UK;Wolfson Laboratory for Environmental Geochemistry, Research School of Earth Sciences at UCL-Birkbeck, University of London, Gower Street, London WC1E 6BT, UK;Department of Earth Sciences, UCL, Gower Street, London WC1E 6BT, UK;Wolfson Laboratory for Environmental Geochemistry, Research School of Earth Sciences at UCL-Birkbeck, University of London, Gower Street, London WC1E 6BT, UK
Abstract:The ability to extract arsenic (As) from soils and sediments, and analyze it with accuracy and precision, is of paramount importance, given the high risk that As, even in relatively low concentrations, poses to pore waters and biota. A large number of methods exist for extracting and analyzing total As, and As associated with a variety of operationally defined phase associations, in soils and sediments. We give an overview of methods used at present, and consider potential problems. We strongly recommend adoption of universal standard techniques and certified reference materials, especially for sequential extraction schemes.
Keywords:Analysis   Arsenic   Extraction   Sediment   Sequential extraction   Soil
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