Synthese bindungsisomerer Alkoxy(aroxy)phosphoryl-tricyanmethanide,ein Beitrag zur Pseudohalogenid-Ambivalenz |
| |
| Authors: | H Khler M Kretschmann L Jger |
| |
| Institution: | H. Köhler,M. Kretschmann,L. Jäger |
| |
| Abstract: | Synthesis of Isomeric Alkoxy(aroxy)phosphoryl-tricyanmethanides, a Contribution to the Ambivalency of Pseudohalides The synthesis of a series of alkoxy(aroxy)phosphoryltricyanmethanides of the isomeric types (RO)2P(O)NCC(CN)2 and (RO)2P(O)C(CN)3 is reported. Synthetic routes as well as IR- and 31P-NMR spectra are indicating close relations of the new compounds to homologeous phosphoryl-pseudohalides (RO)2P(O)NCY and (RO)2P(O)YCN (Y: NCN, O). Thus the presented results are clearly emphasizing the pseudochalcogen-character of the C(CN)2-group. |
| |
| Keywords: | |
|
|
