Über Chalkogenolate. 168. Reaktion von N,N′-Diphenylformamidin mit Kohlenstoffdisulfid 1. Darstellung und Eigenschaften von N,N′-Diphenyl-N-form-imidoyldithiocarbamaten |
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Authors: | W Eul G Gattow |
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Abstract: | On Chalcogenolates. 168. Reaction of N,N′-Diphenyl Formamidine with Carbon Disulfide. 1. Synthesis and Properties of N,N′-Diphenyl N-Formimidoyl Dithiocarbamates N,N′-Diphenyl formamidine H? N(C6H5)? CH?NC6H5 reacts in different solvents with CS2 in the presence of an alkali metal hydroxide to produce N,N′-diphenyl N-formimidoyl dithiocarbamate solvates. The properties of the prepared compounds (L = H2O, acetonitrile, dioxane, dimethoxyethane, acetone, and mixed solvates) and of the Tl, Ba, and Pb salts are described. |
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