Spektroskopische Untersuchungen an Eisen(II)-nitrosodicyan-methanid- und -nitrosocarbamoylcyanmethanid-Komplexen [Fe(NOC(CN)2)2(C5H5N)4] und [Fe(NOC(CN)C(O)NH2)2(C5H5N)2] |
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Authors: | V V Skopenko N N Gerasim
uk S I Tjuchtenko H Khler |
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Institution: | V. V. Skopenko,N. N. Gerasimčuk,S. I. Tjuchtenko,H. Köhler |
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Abstract: | Spectroscopic Investigations of the Iron(II) Nitrosodicyanomethanide and Nitrosocarbamoylcyanomethanide Complexes Fe(NOC(CN)2)2(C5H5N)4] and Fe(NOC(CN)C(O)NH2)2(C5H5N)2] The syntheses of new iron(II) complexes of the nonlinear pseudohalides NOC(CN)2]? and NOC(CN)C(O)NH2]? is reported. The Structures of the compounds are discussed on the basis of IR, Mößbauer, 13C, and 14N NMR spectra as well as of the results of magnetic measurements. |
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