Properties of fluoroantimonates(III) complexes with amino acids |
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| Authors: | L A Zemnukhova T A Babushkina T P Klimova N V Makarenko E V Kovaleva |
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| Institution: | 1. Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, pr. 100-letiya Vladivostoka 159, Vladivostok, 690022, Russia
2. Nesmeyanov Institute of Elementoorganic Compounds, Russian Academy of Sciences, Moscow, Russia
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| Abstract: | Crystalline complex fluoroantimonates(III) with amino acids (glycine, β-alanine, DL-serine, DL-valine, L-leucine, and L-phenylalanine) have been prepared. The complexes stability in aqueous solutions has been studied with the cementation method. 1H NMR studies of aqueous solutions of the amino acids complexes with SbF3 at pH 1–6 and room temperature are reported. Preparation of polycrystalline metal antimony in aqueous solutions of tetrafluoroantimonates(III) complexes with the protonated amino acids has been demonstrated. |
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