Stereoselective total synthesis of ophiocerin D from d-xylose |
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| Authors: | Gangavaram V.M. Sharma Krishna Damera |
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| Affiliation: | aD-211, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | A stereoselective total synthesis of ophiocerin D is reported by a combination of a ‘chiron’ approach and an asymmetric synthesis, from d-xylose. Of the four stereogenic centers, the vic diols C3/C4 and C5/C6 were obtained by Sharpless asymmetric dihydroxylation and from d-xylose, respectively. |
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