The i.r. and Raman spectra of solid trichloroacetonitrile期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The i.r. and Raman spectra of solid trichloroacetonitrile

Affiliation:	1. Dipartimento di Chimica “Giacomo Ciamician”, Università di Bologna, Via F. Selmi 2, 40126 Bologna (Italy);2. Center for Astrochemical Studies, Max Planck Institut für extraterrestrische Physik Gießenbachstraße 1, 85748 Garching bei München (Germany);3. Dipartimento di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale del Risorgimento 4, 40136 Bologna (Italy);4. INAF-Osservatorio Astrofisico di Arcetri, Largo Enrico Fermi 5, 50125, Firenze (Italy);5. Univ Rennes, Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR–UMR6226, 35000 Rennes (France);6. Université Paris-Saclay, CNRS, Institut des Sciences Moléculaires d’Orsay, 91405 Orsay (France);7. SOLEIL Synchrotron, AILES beamline, l’Orme des Merisiers, Saint-Aubin, 91190 Gif-sur-Yvette, (France);8. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Mestre (Italy)

Abstract:	The i.r. and Raman spectra of polycrystalline films of CCl₃CN have been recorded at liquid nitrogen temperature. Chlorine isotope splitting has been resolved for the v₃ fundamental and crystal splittings have been observed for five of the fundamentals. A possible crystal structure is discussed. Raman wavenumbers and depolarization ratios are included for liquid CCl₃CN.

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