Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe |
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| Authors: | Díaz-Requejo M Mar Belderraín Tomás R Nicasio M Carmen Trofimenko Swiatoslaw Pérez Pedro J |
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| Affiliation: | Departamento de Química y Ciencia de Materiales, Universidad de Huelva, Campus de El Carmen, 21071-Huelva, Spain. |
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| Abstract: | The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen bond of cyclohexane and benzene, as well as into the primary C-H bonds of the methyl groups of toluene and mesitylene, in moderate to high yield. |
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