Enantioselective metallo-organocatalyzed preparation of cyclopentanes bearing an all-carbon quaternary stereocenter |
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Authors: | Montaignac Benjamin Praveen Chandrasekaran Vitale Maxime R Michelet Véronique Ratovelomanana-Vidal Virginie |
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Institution: | E.N.S.C.P., Chimie-ParisTech, UMR 7223, Laboratoire Charles Friedel (LCF), 75005 Paris, France. |
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Abstract: | Enantioselective metallo-organocatalyzed carbocyclizations of formyl-alkynes have been developed. The cooperation between aminocatalysis and a chiral copper(I) complex granted access to enantio-enriched cyclopentanes through the challenging formation of all-carbon quaternary stereocenters. |
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