Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine |
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Authors: | Lamani Manjunath Guralamata Ravikumara Siddappa Prabhu Kandikere Ramaiah |
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Institution: | Department of Organic chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India. |
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Abstract: | An efficient aerobic reduction of olefins, internal as well as terminal, is developed using guanidine as an organocatalyst. A remarkable chemoselectivity in reduction has been demonstrated in the presence of a variety of functional groups and protective groups and a selective reduction of a terminal olefin in the presence of an internal olefin is revealed. |
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