Gels of shape-persistent macrocycles: the role of the interior |
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| Authors: | Vollmeyer Joscha Jester Stefan-S Eberhagen Friederike Prangenberg Thomas Mader Werner Höger Sigurd |
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| Affiliation: | Rheinische Friedrich-Wilhelms-Universit?t Bonn, Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany. |
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| Abstract: | The aggregation of shape-persistent macrocycles with an empty cavity, an undecyldiether strand and a tetraethylene glycol strand leads in all cases to a macroscopic gelation of the solvent. However, the gelation temperatures are fine-tuned by the intraannular substituents. |
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