A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions |
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Authors: | Zhang Jingming Biradar Ankush V Pramanik Sanhita Emge Thomas J Asefa Tewodros Li Jing |
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Institution: | Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Rd., Piscataway, NJ 08854, USA. |
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Abstract: | A new layered MOF material Co(Hoba)(2)·2H(2)O] (1) (H(2)oba = 4,4'-oxybis(benzoic acid)) has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin epoxidation reactions. Both high conversion (96%) and high selectivity of epoxide products (96%) are achieved. |
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