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A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions
Authors:Zhang Jingming  Biradar Ankush V  Pramanik Sanhita  Emge Thomas J  Asefa Tewodros  Li Jing
Institution:Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Rd., Piscataway, NJ 08854, USA.
Abstract:A new layered MOF material Co(Hoba)(2)·2H(2)O] (1) (H(2)oba = 4,4'-oxybis(benzoic acid)) has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin epoxidation reactions. Both high conversion (96%) and high selectivity of epoxide products (96%) are achieved.
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