Abstract: | Granular films of Co-cluster/C60 mixtures have been prepared by the co-deposition of well defined Co clusters (mean diameter 4.5 nm) and C60 fullerenes onto a cold (35 K) substrate. Films having a Co cluster volume fraction show a resistivity , typical for tunneling with a Coulomb barrier. The tunneling magnetoresistance (TMR) has a value of TMR (% for and is decreasing by almost one order of magnitude going to . We explain this unusual decrease of the TMR with increasing as caused by electron-doping of the C60 fullerenes due to the known charge transfer process occurring between transition metal surface and C60. Increasing electron doping may lead to an increasing probability for spin-flip processes within the tunneling barrier, resulting in a decrease of the TMR.Received: 17 March 2004, Published online: 3 August 2004PACS: 75.47.-m Magnetotransport phenomena; materials for magnetotransport - 73.40.Gk Tunneling - 73.40.Rw Metal-insulator-metal structures |