| 全氟烷基磺酰碘的化学 |
| |
| 引用本文： | 黄维垣,胡里清. 全氟烷基磺酰碘的化学[J]. 化学学报, 1988, 46(11): 1148-1149 |
| |
| 作者姓名： | 黄维垣 胡里清 |
| |
| 作者单位： | 中国科学院上海有机化学研究所 |
| |
| 摘 要： | 报导了全氟烷基亚磺酸银与碘之间在二氯甲烷中的低温反应(-30℃). 生成相应的全氟烷基磺酰碘. 并用^1^9F NMR证实其结构, 磺酰碘与各种稀烃反应则可产生二种系列的加成物RfSO2CH2CHIR和RfCH2CHIR.
|
| 关 键 词： | 磺酸P 全氟代烃 酰碘 |
Chemistry of perfluoroalkane sulfonyl iodide |
| |
| HUANG WEIYUAN,HU LIQING. Chemistry of perfluoroalkane sulfonyl iodide[J]. Acta Chimica Sinica, 1988, 46(11): 1148-1149 |
| |
| Authors: | HUANG WEIYUAN HU LIQING |
| |
| Abstract: | The reaction between silver perfluoroalkanesulfinates Cl(CF2)nSO2Ag (n = 4, 6) and iodine in dichloromethane at low temperature (e.g., -30 ? resulted in the formation of the corresponding perfluoroalkanesulfonyl iodides, which were identified by their 19F NMR spectra. The sulfonyl iodide generated in situ reacted with various olefins to form two series of adducts, namely the normal adducts, e.g. Me(CH2)3CHICH2SO2(CF2)nCl, and the adducts resulting from the simultaneous loss of the SO2 moiety, e.g. Cl2CICH2(CF2)nCl, in yields varying from moderate to good. |
| |
| Keywords: | SULFONIC ACID P PERFLUORO-HYDROCARBON ACYL IODIDE |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
|
点击此处可从《化学学报》下载全文 |
|
