Medium-sized carbocycles by a zirconocene-catalyzed tandem formal ring expansion-magnesation reaction of alkenyl-substituted cyclic enol ethers |
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| Authors: | Barluenga José Alvarez-Rodrigo Lucía Rodríguez Félix Fañanás Francisco J |
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| Affiliation: | Instituto Universitario de Química OrganometAlica Enrique Moles, Unidad Asociada al CSIC, Universidad de Oviedo, JuliAn Clavería 8, 33006-Oviedo, Spain. barluenga@uniovi.es |
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| Abstract: | A new regio- and stereoselective zirconocene-catalyzed reaction for the synthesis of medium-sized rings is described. The global reaction supposes a formal ring expansion of a cyclic enol ether to give a functionalized carbocycle. |
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