Safety improvement of lithium ion batteries by organo-fluorine compounds |
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Authors: | Yuki Matsuda Tsuyoshi Nakajima Yoshimi Ohzawa Meiten Koh Akiyoshi Yamauchi Michiru Kagawa Hirokazu Aoyama |
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Institution: | aDepartment of Applied Chemistry, Aichi Institute of Technology, Yakusa, Toyota 470-0392, Japan;bDaikin Industries, Ltd., Settsu, Osaka 566-8585, Japan |
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Abstract: | Thermal stability, electrochemical oxidation stability and charge/discharge characteristics of natural graphite powder were investigated by mixing of five fluoro-carbonates with 1 mol/L LiClO4–EC/DEC/PC (1:1:1 vol.). DSC study revealed that thermal stability of the electrolyte solution was improved by mixing of fluoro-carbonates by 10.0–33.3 vol.%. Electrochemical oxidation stability was also improved. Oxidation currents for Pt electrode significantly decreased by mixing of fluoro-carbonates. In the fluoro-carbonate-mixed electrolyte solutions, electrochemical reduction of PC decreased with increasing concentration of fluoro-carbonate and current density. As a result, first coulombic efficiency for natural graphite electrode increased, that is, irreversible capacity decreased in the fluoro-carbonate-mixed solutions. |
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Keywords: | Organo-fluorine compound Thermal stability Oxidation stability Graphite electrode Lithium ion battery |
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