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An Approach towards Synthesis of Nanoarchitectured LiNi1/3Co1/3Mn1/3O2 Cathode Material for Lithium Ion Batteries
Authors:Weibo Hua  Yanjie Wang  Yanjun Zhong  Guoping Wang  Benhe Zhong  Baizeng Fang  Xiaodong Guo  Shixuan Liao  Haijiang Wang
Affiliation:1. College of Chemical Engineering, Sichuan University, Chengdu, Sichuan 610065, China;2. Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, BC, Canada, V6T 1Z3;3. Institute for Fuel Cell Innovation, National Research Council of Canada, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5, Canada;4. College of Chemical Engineering, University of South China, Hengyang, Hunan 421001, China
Abstract:To explore advanced cathode materials for lithium ion batteries (LIBs), a nanoarchitectured LiNi1/3Co1/3Mn1/3O2 (LNCM) material is developed using a modified carbonate coprecipitation method in combination with a vacuum distillation‐crystallisation process. Compared with the LNCM materials produced by a traditional carbonate coprecipitation method, the prepared LNCM material synthesized through this modified method reveals a better hexagonal layered structure, smaller particle sizes (ca. 110.5 nm), and higher specific surface areas. Because of its unique structural characteristics, the as‐prepared LNCM material demonstrates excellent electrochemical properties including high rate capability and good cycleability when it is utilized as a cathode in the lithium ion battery (LIB).
Keywords:cathode materials  nanoarchitectured  coprecipitation  electrochemical properties  lithium ion battery
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