Synthesis and Catalytic Study of Ruthenium Carbene Catalyst Containing a Zn‐Porphyrin Ligand |
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| Authors: | Ying Xu Huizhu Zhang Xinyuan Wang Guiyan Liu |
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| Institution: | 1. Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic‐Organic Hybrid Functional Material Chemistry (Tianjin Normal University), Ministry of Education;2. College of Chemistry, Tianjin Normal University, Tianjin, 300387, China |
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| Abstract: | A ruthenium carbene complex containing a Zn‐porphyrin ligand has been developed. The complex was characterized by 1H NMR, IR, HRMS and elemental analysis. The catalytic activity of the ruthenium carbene complex for olefin metathesis reactions was also investigated. The complex exhibited excellent performance for both ring‐closing and cross metathesis reactions at 35°C. |
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| Keywords: | olefin metathesis ruthenium carbene catalyst Zn‐porphyrin |
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