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Lithium electrochromism of atmospheric pressure plasma jet-synthesized NiO x C y thin films
Authors:Yung-Sen Lin  Di-Jiun Lin  Lu-Yan Chiu  Sheng-Wei Lin
Institution:1. Department of Chemical Engineering, Feng Chia University, No.100, Wenhwa Rd., Seatwen, Taichung, Taiwan, 40724, Republic of China
Abstract:Reversible lithium intercalation and deintercalation behavior of atmospheric pressure plasma jet (APPJ)-synthesized organonickel oxide (NiO x C y ) thin films under various substrate distances is testified in an electrolyte (1?M LiClO4–propylene carbonate solution) at low driving voltages from ?0.5 to 1.5?V. Fast responses of 2?s bleaching at ?0.5?V and 6?s coloration at +1.5?V are accomplished for the nano-porous NiO x C y thin films. This study reveals that a rapid synthesis of electrochromic NiO x C y thin films in a single process via APPJ by 21?s is investigated. This study presents a noteworthy electrochromic performance in a light modulation with up to 43% of transmittance variation and a coloration efficiency of 36.3?cm2/C at a wavelength of 830?nm after 200?cycles of cyclic voltammetry measurements.
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