Reaction of 3-Carene with Some Nitrating Agents |
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| Authors: | Bakhvalov O V Bagryanskaya I Yu Gatilov Yu V Korchagina D V Barkhash V A |
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| Institution: | (1) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia |
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| Abstract: | From the reaction products obtained by treating 3-carene with dinitrogen tetroxide a crystalline compound N-(1R,6R)-3-methyl-6-(1-methyl-1-nitroxyethyl)cyclohex-3-enyl]-N'-{1S,6S)-4- methyl-6(1- methyl-1-nitroxyethyl)cyclo-hex-3-enyl]-E-diazene-N,N'-dioxide was isolated. Mainly nitrate of  -terpineol formed in reaction of 3-carene with 70% nitric acid. |
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