| 长链烷胺及手性钛的螯合物Ti[(OC2H4)3N][OCH(CH3)2]在层状V2O5中的插层行为 |
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| 引用本文： | 郭宪吉,侯文华,陈静,许爱荣.长链烷胺及手性钛的螯合物Ti[(OC2H4)3N][OCH(CH3)2]在层状V2O5中的插层行为[J].化学学报,2006,17(17):1770-1774. |
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| 作者姓名： | 郭宪吉 侯文华 陈静 许爱荣 |
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| 作者单位： | 南京大学化学化工学院介观化学教育部重点实验室，南京大学化学化工学院介观化学教育部重点实验室，南京工业大学理学院应用化学系，郑州大学化学系 南京210093郑州大学化学系，郑州450052，南京210093，南京210009，郑州450052 |
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| 基金项目： | 国家自然科学基金(No.29903005)，国家重大基础研究规划课题(No.2003CB615804)资助项目. |
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| 摘 要： | 用一种简便快速方法合成了一系列长链有机胺插层V2O5化合物. 用粉末X射线衍射(XRD)、红外光谱(FT-IR)、漫反射紫外-可见光谱(DR UV-VIS)等手段对插层产品的结构进行了表征. 除了正十六胺插层V2O5产品外, 其它长链烷胺插层V2O5产品的层间距d001与长链烷胺碳数n之间具有良好的线性关系: d001＝0.160nC＋0.731 nm. 正十六胺与V2O5反应后生成两个插层相, 一个相的层间距d001为4.01 nm, 另一相的d001为3.20 nm. 此外, 研究了手性钛的螯合物Ti(OC2H4)3N]OCH(CH3)2] (记为TEAIP)在V2O5层间的插层行为, 得到相应的插层产品.
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| 关 键 词： | 有机胺 手性钛的螯合物 插层 层状V2O5 结构表征 |
| 收稿时间： | 03 3 2006 12:00AM |
| 修稿时间： | 2006-03-032006-03-03 |
Intercalation Behavior of Long-chain n-Alkylamine and Chiral Ti[(OC2H4)3N][OCH(CH3)2] in Layered V2O5 |
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| GUO,Xian-Ji,HOU,Wen-Hua,CHEN,Jing,XU,Ai-Rong.Intercalation Behavior of Long-chain n-Alkylamine and Chiral Ti[(OC2H4)3N][OCH(CH3)2] in Layered V2O5[J].Acta Chimica Sinica,2006,17(17):1770-1774. |
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| Authors: | GUO Xian-Ji HOU Wen-Hua CHEN Jing XU Ai-Rong |
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| Institution: | a Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chimical Engineering, Nanjing University, Nanjing 210093; epartment of Chemtstry, Zhengzhou University, Zhengzhou 450052;C Department of Applied Chemistry, School of Science, Nanjing University of Technology, Nanjing 210009 |
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| Abstract: | A series of long-chain n-alkylamine-intercalated layered V2O5 materials were synthesized through a simple and quick route. X-ray diffraction (XRD), framework FT-IR and diffuse reflectance UV-visible spectroscopy (DR UV-Vis) were employed to investigate the structure of the obtained products. An excellent linear relationship between the basal interlayer distances of the n-alkylamine-intercalated V2O5 and the number of carbon atoms in the n-alkyl chain (d001=0.160nC 0.731 nm) with an exception for n-hexadecanamine was presented. n-Hexadecanamine-intercalated V2O5 was composed of two guest-intercalated layered phases, and the basal interlayer distances (d001) of the two phases were 4.01 and 3.20 nm, respectively. The intercalation behavior of titanium(IV) (triethanolaminato)-isopropoxide (TEAIP) in layered V2O5 was also investigated, and the TEAIP intercalated layered V2O5 product was obtained. |
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| Keywords: | organic amine chiral titanium(IV) pentacoordinated complex intercalation layered V_2O_5 characterization of structure |
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