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The chemistry of carbonyl clusters of transition metals containing labile and hemilabile ligands. Synthesis,reactivity, and prospects for application
Authors:S. P. Tunik
Affiliation:(1) Department of Chemistry, St. Petersburg State University, 26 Universitetskii prosp., 198504 St.-Petersburg, Russian Federation
Abstract:The methods of synthesis, structural features, and the reactivity of substituted carbonyl clusters of transition metals containing labile and hemilabile ligands are considered.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2547–2559, December, 2004.
Keywords:carbonyl clusters  transition metals  labile ligand  hemilabile ligands  synthesis  structure  reactivity  mechanism of substituted reactions  catalysis
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