Chemomicrobial synthesis of (R)- and (S)-lavandulol |
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Authors: | Anna GliszczyńskaRados?aw Bonikowski Józef Kula Czes?aw WawrzeńczykKornelia Cio?ak |
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Institution: | a Institute of General Food Chemistry, Technical University of Lodz, Stefanowskiego 4/10, 90-924 Lodz, Poland b Department of Chemistry, Wroclaw University of Environmental and Life Sciences, C.K. Norwida 25/27, 50-375 Wroc?aw, Poland |
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Abstract: | (R)- and (S)-Lavandulol are important compounds in the cosmetics industry and in pheromone research. We have developed syntheses of (R)- and (S)-lavandulol from (S)- and (R)-limonene, respectively, by microbial Baeyer-Villiger oxidation of the intermediate unsaturated hydroxy ketone. It has been found that the same strain of Acremonium roseum can be successfully used in the key step of the synthesis of both enantiomers of lavandulol. |
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Keywords: | Lavandulol Limonene Baeyer-Villiger oxidation Acremonium roseum Terpenes |
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