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A convenient synthesis of gamma-functionalized cyclopentenones
Authors:Lahmar Nour  Ben Ayed Taïcir  Bellassoued Moncef  Amri Hassen
Institution:Laboratoire de Chimie Organique & Organométallique, Faculté des Sciences, Campus Universitaire 2092-Tunis, Tunisie. lahmar_nour@lycos.com
Abstract:The synthesis of gamma-functionalized cyclopentenones was carried out in a few steps, starting firstly with the preparation of nitroketonic intermediates 2, which were readily transformed into 1,4-diketones using the Nef conversion. The intramolecular cyclization of the gamma-diketones 3 in a basic medium, led to the functionalized cyclopentenones 4.
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