A convenient synthesis of gamma-functionalized cyclopentenones |
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Authors: | Lahmar Nour Ben Ayed Taïcir Bellassoued Moncef Amri Hassen |
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Institution: | Laboratoire de Chimie Organique & Organométallique, Faculté des Sciences, Campus Universitaire 2092-Tunis, Tunisie. lahmar_nour@lycos.com |
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Abstract: | The synthesis of gamma-functionalized cyclopentenones was carried out in a few steps, starting firstly with the preparation of nitroketonic intermediates 2, which were readily transformed into 1,4-diketones using the Nef conversion. The intramolecular cyclization of the gamma-diketones 3 in a basic medium, led to the functionalized cyclopentenones 4. |
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