Lipase-catalyzed glucose fatty acid ester synthesis in ionic liquids |
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Authors: | Ganske Franka Bornscheuer Uwe T |
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Institution: | Department of Technical Chemistry and Biotechnology, Institute of Chemistry and Biochemistry, Greifswald University, Germany. |
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Abstract: | reaction: see text] Glucose fatty acid ester synthesis with poly(ethylene glycol)-modified Candida antarctica lipase B (CAL-B) was performed in pure 1-butyl-3-methyl imidazolium tetrafluoroborate BMIM]BF(4)] (30% conversion) and in pure 1-butyl-3-methyl imidazolium hexafluorophosphate BMIM]PF(6)] (35% conversion). In a solvent system composed of ionic liquid and 40% t-BuOH conversions up to 90% and isolated yields of up to 89% were achieved using fatty acid vinyl esters as acyl donors and commercial CAL-B. |
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