Nonenzymatic sensor for hydrogen peroxide based on the electrodeposition of silver nanoparticles on poly(ionic liquid)-stabilized graphene sheets |
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Authors: | Qi Wang Yanbin Yun |
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Institution: | 1. School of Science, Xidian University, Xi’an, 710071, People’s Republic of China 2. Institute of Analytical Science/Shaanxi Provincial Key Laboratory of Electroanalytical Chemistry, Northwest University, Xi’an, 710069, People’s Republic of China 3. College of Environmental Science & Engineering, Beijing Forestry University, Beijing, 100083, People’s Republic of China
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Abstract: | We have developed a nonenzymatic sensor for hydrogen peroxide (HP) that is based on a new kind of nanocomposite consisting of silver nanoparticles (AgNPs) electrodeposited on a basic film of a poly(ionic liquid) containing graphene. The nanocomposite was characterized by scanning electron microscopy, energy dispersive X-ray studies, cyclic voltammetry, and chronoamperometry. The AgNPs on the basic composite film provide the electrode with enhanced sensitivity in that the signal obtained for HP is 10-fold improved in the best case. The sensor exhibits good linear response in the 0.1 μM to 2.2 mM HP concentration range, and the detection limit is 0.05 μM (at S/N?=?3). | |
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