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Cathodic performance of V2O5 nanowires and reduced graphene oxide composites for lithium ion batteries
Institution:1. Department of Nano Fusion Technology, Pusan National University, Miryang 607-706, Republic of Korea;2. Battery Research Center, Korea Electrotechnology Research Institute, Gyeongsangnam-do 642-120, Republic of Korea;3. Busan Center, Korea Basic Science Institute, Busan 642-120, Republic of Korea
Abstract:In this study, vanadium pentoxide (V2O5) nanowires (NWs) with a diameter of 100–200 nm and a length of up to several micrometers as cathode for lithium ion batteries are synthesize using an electrospinning method. The reduced graphene oxide (rGO) and V2O5 NWs (GVO) composites are form by wet mixing the electrospun V2O5 NWs and rGO. Surface morphologies, microstructure and elemental mapping, and chemical bonding states of the composites are characterize. The initial and 60 cycles discharge capacities of GVO composite composed of 1 wt% rGO show up to 225 mAh g?1 and 125 mAh g?1, even higher than pure V2O5 NWs, when the lithium ion battery cycled between 2.0 and 4.0 V with a rate of 0.2 C, because of highly conductive rGO. The GVO composite could be promising as a high performance cathode for lithium ion batteries.
Keywords:Vanadium oxide  Reduced graphene oxide  Nanowires  Cathode materials
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