| 烯丙基碘和锡与醛的选择加成反应 |
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| 引用本文： | 姚丹姝. 烯丙基碘和锡与醛的选择加成反应[J]. 合成化学, 1998, 6(3): 315-318 |
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| 作者姓名： | 姚丹姝 |
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| 作者单位： | 东北大学黄金学院 |
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| 摘 要： | 含活性基团的醛可与烯丙碘和锡粉直接进行亲核加成反应，得到高烯丙基的醇，水的存在不利于此反应的进行，与烯丙基溴相比，烯丙基碘反应活性更强，可在短时间内得较高的产率。
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| 关 键 词： | 烯丙基碘 锡粉 加成反应 醛 醇 高烯丙基型 |
Selective Addition of Aldehydes by Allyl Iodine and Tin |
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| Yao,Dan Shu. Selective Addition of Aldehydes by Allyl Iodine and Tin[J]. Chinese Journal of Synthetic Chemistry, 1998, 6(3): 315-318 |
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| Authors: | Yao Dan Shu |
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| Abstract: | Aldehyde containing functional groups can react with allyl iodine and tin directly, water is of no advantage to the reaction. Comparing with allyl bromide, allyl iodine is more active and can give homoallyl alcohol in good yields. |
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| Keywords: | Allyl iodine Aldehyde Tin Selective allylation. |
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