DAR成色剂结构与性能的关系 |
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引用本文: | 刘玉婷,吕峰,邹竞,张大德,姚祖光. DAR成色剂结构与性能的关系[J]. 影像科学与光化学, 2004, 22(4) |
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作者姓名: | 刘玉婷 吕峰 邹竞 张大德 姚祖光 |
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作者单位: | 华东理工大学,精细化工研究所,上海,200237;陕西科技大学化学与化工学院,陕西,咸阳,712081;华东理工大学,精细化工研究所,上海,200237;中国乐凯胶片集团公司,河北,保定,071054 |
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基金项目: | 中国乐凯胶片集团公司资助项目 |
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摘 要: | 通过分析DAR成色剂的结构和作用机理,讨论了其结构与照相性能之间的关系.DAR成色剂的结构可表示为:Cp—L—A,其中Cp代表成色剂母体,A代表促进显影的功能基团即增强基团,L代表连接基团同时也有吸附功能即吸附基团.本文指出:当吸附基团和增强基团相同时,母体对照相性能影响不大;当母体及增强基团相同时,吸附基团的吸附性越强,照相性能越好;当母体及吸附基团相同时,增强基团的感染显影作用越强,照相性能越好.
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关 键 词: | DAR成色剂 结构 作用机理 性能 |
Relation Between DAR Coupler's Structure and Property |
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Abstract: | The relation of the structure of DAR coupler and it's photographic property was reported by analysizing the structure of DAR coupler.The structure of DAR coupler can be represented by Cp-L-A.Cp is the coupler residue;L is the divalent linking group also is the adsorbing group;A is the development accelerating functional group.In this paper,conclusion were made:the Cp can make no effect apparently on photographic property when L and A are the same.The stronger of the development accelerating functional group,the better of the DAR coupler's photographic property when Cp and L are the same.The stronger of the adsorbability of adsorbing group,the better of the DAR coupler's photographic property when Cp and A are the same. |
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Keywords: | DAR coupler structure mechanism property |
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