In situ high pressure study of ZIF-8 by FTIR spectroscopy |
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Authors: | Hu Yue Kazemian Hossein Rohani Sohrab Huang Yining Song Yang |
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Affiliation: | Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada. |
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Abstract: | ZIF-8 as a promising storage material was investigated at high pressures up to ~39 GPa by in situ FTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression. |
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