TBHP-mediated oxidative thiolation of an sp3 C-H bond adjacent to a nitrogen atom in an amide |
| |
| Authors: | Tang Ri-Yuan Xie Ye-Xiang Xie Yi-Li Xiang Jian-Nan Li Jin-Heng |
| |
| Affiliation: | State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. |
| |
| Abstract: | The first example of molecular sieve-promoted TBHP-mediated direct oxidative thiolation of an sp(3) C-H bond adjacent to a nitrogen atom with disulfides under metal-free conditions, which allows for preparation of numerous S,N-containing compounds, is presented. Moreover, diverse benzothiazoles and a fipronil analog can be synthesized through this strategy. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
