Diffusion of Sr and Zr in BaTiO3 single crystals |
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Authors: | Sylvia Koerfer Roger A De Souza Han-Ill Yoo Manfred Martin |
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Institution: | aInstitute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, 52056 Aachen, Germany;bSchool of Materials Science and Engineering, Seoul National University, Seoul 151-742, South Korea |
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Abstract: | The diffusion of strontium and zirconium in single crystal BaTiO3 was investigated in air at temperatures between 1000 °C and 1250 °C. Thin films of SrTiO3, deposited by spin coating a precursor solution and thin films of zirconium, deposited onto the sample surfaces by sputtering, were used as diffusion sources. The diffusion profiles were measured by SIMS depth profiling on a time-of-flight secondary ion mass spectrometer (ToF-SIMS). The diffusion coefficients of strontium and zirconium were given by DSr = 3.6 × 102.0±4.4 exp−(543 ± 117) kJ mol−1/(RT)] cm2 s−1 and DZr = 1.1 × 101.0±2.1 exp−(489 ± 56) kJ mol−1/(RT)] cm2 s−1. The results are discussed in terms of different diffusion mechanisms in the perovskite structure of BaTiO3. |
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Keywords: | Barium titanate Cation diffusion SIMS |
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