Abstract: | Two new steroid glycosides of the spirostan series have been isolated from the fruit ofAllium cepa L. (family Liliaceae): alliospirosides C and D. On the basis of chemical transformations and spectral characteristics it has been established that the aglycon of both glycosides is a new steroid sapogenin — cepagenin — having the structure of (24S,25R)-spirost-5-ene-1 ,3 ,24-triol. Alliospirosides C and D are cepagenin 1-O-O- -L-rhamnopyranosyl-(1 2) -L-arabinopyranoside] and 1-O-O- -L-rhamnopyranosyl-(1 2)-O- -D-galactopyranoside], respectively.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 843–849, November–December, 1987. |