Synergistic extraction of hexavalent actinides by HTTA and neutral donors-II

Synergistic extraction studies on Np(VI) and Pu(VI) have been carried out as a part of the programme on the synergistic extraction of hexavalent actinides. Extraction of Np(VI) and Pu(VI) were carried out by mixtures of HTTA and TBP in benzene from aqueous perchlorate and nitrate media. Equilibrium constant values for the various reaction equilibria involved were calculated from the data obtained by using slope-ratio as well as Job’s method. The extraction of Np(VI) by the synergistic mixture from 1M nitric acid indicated that the species NpO₂ (TTA) (NO₃). TBP was not involved in the extraction. The log values of K_A, K_AB and β_AB were −1.5, 2.92 and 4.43, respectively for Np(VI) and −1.63, 2.50 and 4.13 respectively for Pu(VI).