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Synthesis and thermal characterization of copper and calcium mixed phosphates
Authors:E C da Silva Filho  Oberto G da Silva  Maria G da Fonseca  Luiza N H Arakaki  C Airoldi
Institution:1.Química,Universidade Federal do Piauí,Bom Jesus,Brazil;2.Departamento de Química, CCEN,Universidade Federal da Paraíba,Jo?o Pessoa,Brazil;3.Instituto de Química,Universidade Estadual de Campinas,Campinas,Brazil
Abstract:A series of compounds with composition of Ca1–xCuxHPO4, where x varied from 0.05 to 0.5 were synthesized by precipitation method. The compounds were characterized by elemental analysis, X-ray diffraction, infrared spectroscopy, scanning electron microscopy, and thermogravimetry. The chemical stabilities of solids were investigated at several pH. Elemental analysis of copper, calcium and phosphorus are in agreement with the proposed composition. The formation of lamellar phosphates was evidenced. The stability of the set of compounds was better for samples with high copper content.
Keywords:calcium phosphate  copper phosphate  thermogravimetry
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