| 6—磺酰香豆素—β—CD的合成及分子识别性质初探 |
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| 引用本文： | 赵瑜,李隆弟.6—磺酰香豆素—β—CD的合成及分子识别性质初探[J].光谱学与光谱分析,1998,18(4):464-467. |
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| 作者姓名： | 赵瑜 李隆弟 |
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| 作者单位： | 清华大学化学系 |
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| 摘 要： | 本文合成和鉴定了具有分子识别功能的发光试剂６－磺酰香豆素－ＣＤ（吣－Ｃｓ－β－ＣＤ）。在碱怀条件下，经过足够的光照，它有产生强而稳定的荧光，以其为腐朽 ，研究了对客体环己醇，环己烯，环己烷和溴代环己烷分子的认别性能，计算出相应的包结常数和识别因子。
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| 关 键 词： | 磺酰香豆素 环糊精衍生物 合成 分子识别 环己醇 |
Synthesis and molecular recognition study of 6-Cs-beta-CD] |
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| Y Zhao,L Li,A Tong.Synthesis and molecular recognition study of 6-Cs-beta-CD][J].Spectroscopy and Spectral Analysis,1998,18(4):464-467. |
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| Authors: | Y Zhao L Li A Tong |
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| Institution: | Department of Chemistry, Tsinghua University, 100084 Beijing. |
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| Abstract: | The reagents 6-Cs-beta-CD with molecular recognition function were synthesized and confirmed. Both basic condition and enough illumination were necessary for obtaining stable and strong fluorescence. With 6-Cs-beta-CD as the host, cyclohexanol, cyclohexene, cyclohexane and bromocyclohexane as the guest, the recognition properties were studied. The affinity of 6-Cs-beta-CD and the guest is distinct with different hydrophobicity of the guest. |
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