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Study on the Atomization Process of Lithium in Electrothermal Atomic Absorption Spectrometry
作者姓名:Yan  Xiuping
作者单位:Yan Xiuping(Department of Chemistry,Taizhou Teachers College,Taizhou)Lin Tiezheng(Dalian Institute of Chemical Physics,Academia Sinica)
摘    要:A new method for determining the kinetic order and activation energy for atom formation in electrothermal atomic absorption spec-trometry is proposed. The assumption of first order kinetics for atom formation and the steady-state approximation which appeared in the previous models is avoided in the proposed method. The kinetic parameters for atom formation of Li have been obtained, and the effect of the amount of analysed sample, ashing temperature, atomization temperature, heating rate, gas flow and tube surface on the atomization of Li has also been investigated.


Study on the Atomization Process of Lithium in Electrothermal Atomic Absorption Spectrometry
Yan Xiuping.Study on the Atomization Process of Lithium in Electrothermal Atomic Absorption Spectrometry[J].Chemical Research in Chinese University,1989(1).
Authors:Yan Xiuping
Abstract:A new method for determining the kinetic order and activation energy for atom formation in electrothermal atomic absorption spec-trometry is proposed. The assumption of first order kinetics for atom formation and the steady-state approximation which appeared in the previous models is avoided in the proposed method. The kinetic parameters for atom formation of Li have been obtained, and the effect of the amount of analysed sample, ashing temperature, atomization temperature, heating rate, gas flow and tube surface on the atomization of Li has also been investigated.
Keywords:Atomic absorption  Atomization peocess  Kinetic parameters
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