A simple calorimeter for the heats of mixing study of associated liquids: Enthalpy of hydrogen bonded ethanol-butylamine complex |
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Authors: | Shirish D Pradhan and Gopal Pathak |
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Institution: | (1) National Chemical Laboratory, 411008 Pune, India |
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Abstract: | A simple dewar type calorimeter has been constructed to determine the enthalpy of mixing in dilute concentration range and
its performance checked by determining the heats of mixing of cyclohexane (l)-n-hexane (2) and ethanol (1)n-hexane (2) systems. The heats of mixing ofn-butylamine withn-hexane and ethanol have been determined at 30° C. The enthalpy of ethanol-butylamine complex calculated by a thermochemical
cycle was found to be-40.3 kJ/mol.
NCL Communication No. 2492 |
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Keywords: | Calorimeter ethanol-butylamine heats of mixing hydrogen bonding thermodynamics |
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