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Hydrothermal synthesis of nitrogen-doped carbon dots as a sensitive fluorescent probe for the rapid,selective determination of Hg2+
Authors:Yong Zhang  Na Jing  Junqiu Zhang
Institution:1. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, Chinazhangyong@sxu.edu.cn;3. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, China
Abstract:In the present work, a green synthetic method for producing nitrogen-doped carbon dots (NCDs) by using ammonium citrate and urea is introduced. The obtained NCDs were characterised by transmission electron microscopy, Fourier transform infrared spectra, UV–vis absorption and fluorescence spectra. The results showed that the prepared NCDs were spherical with a size of about 3.5 nm, emitting strong and stable blue fluorescence when excited at 352 nm. It was noting that the NCDs enable sensitive and selective determination of Hg2+ in tap water with a linear range of 0.01–5 mg L?1 based on a possible charge transfer process. The detection limit was 9.4 µg L?1.
Keywords:Hydrothermal synthesis  nitrogen-doped carbon dots  ammonium citrate  urea  Hg2+
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