Unexpected course of Wittig reaction when using cinnamyl aldehyde as a substrate |
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Authors: | Monika Szymczyk |
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Affiliation: | 1. Department of Bioorganic Chemistry, Faculty of Chemistry, Wroclaw University of Science and Technology, Wroclaw, Polandmonika.natalia.szymczyk@gmail.com |
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Abstract: | When trans-cinnamyl aldehyde was used as a substrate of the Wittig reaction, instead of the olefination product, formation of four products with (E)-1,3-diphenylprop-2-en-1-ol and cinnamyl alcohol was observed being quite unexpected ones. The possible mechanism of this unusual reaction has been considered. |
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Keywords: | trans-cinnamyl aldehyde Wittig reaction Wittig olefination |
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