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Polyethylene-based nanocomposite: Structure and properties of poly(vinyl alcohol)/organofunctionalized Mg-doped fluorapatite hybrid
Authors:Shadpour Mallakpour  Marziyeh Khani  Fereshteh Mallakpour  Mohammadhossein Fathi
Affiliation:1. Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, Islamic Republic of Iran;2. Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan, Islamic Republic of Iranmallak777@yahoo.com;4. Biomaterials Group, Department of Materials Engineering, Isfahan University of Technology, Isfahan, Islamic Republic of Iran
Abstract:We report here the production and characterization of polymer nanocomposites (NC)s containing nanoceramics of organofunctionalized Mg-doped fluorapatite (MDFA) in a poly(vinyl alcohol) matrix. First, the MDFA materials were functionalized with N-trimellitylimido-L-leucine modifier through ultrasonic irradiation. The numerous experimental techniques like Fourier transform infrared spectroscopy, X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis were applied to characterize the prepared materials. Thermal analysis of the obtained NCs showed an increase in thermal stability of the NCs when compared to the neat macromolecule.
Keywords:Diacid modifier  Mg-doped fluorapatite  organo-mineral materials  poly(viny/l alcohol)  polymer nanocomposites  ultrasonic-assisted technique
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